2-(4-Fluoro­phen­yl)-2-oxoethyl 4-meth­oxy­benzoate

نویسندگان

  • Hoong-Kun Fun
  • Wan-Sin Loh
  • B. Garudachari
  • Arun M. Isloor
  • M. N. Satyanarayan
چکیده

In the title compound, C(16)H(13)FO(4), the dihedral angle between the benzene rings is 84.28 (8)°. In the crystal, C-H⋯F and C-H⋯O hydrogen bonds link the mol-ecules to form a three-dimensional network. The crystal structure is consolidated by C-H⋯π inter-actions and short F⋯F contacts [2.7748 (14) Å] also occur.

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منابع مشابه

2-(4-Bromo­phen­yl)-2-oxoethyl 2-meth­oxy­benzoate

In the title mol-ecule, C(16)H(13)BrO(4), the dihedral angle between the benzene rings is 85.92 (10)°. In the crystal, mol-ecules are linked into chains along [100] via weak inter-molecular C-H⋯O hydrogen bonds.

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2-(4-Bromo­phen­yl)-2-oxoethyl 4-meth­oxy­benzoate

In the title compound, C(16)H(13)BrO(4), the benzene rings are almost perpendicular to each other, making a dihedral angle of 84.07 (8)°. In the crystal, the mol-ecules are linked into chains along the a axis via inter-molecular C-H⋯O hydrogen bonds. A C-H⋯π inter-action is also observed.

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2-(4-Chloro­phen­yl)-2-oxoethyl 2-meth­oxy­benzoate

In the title compound, C(16)H(13)ClO(4), the two benzene rings make a dihedral angle of 86.38 (8)°. In the crystal, inter-molecular C-H⋯O hydrogen bonds link the mol-ecules to form columns along the a axis. The mol-ecules are also stabilized by a π-π stacking inter-action, with a centroid-centroid distance of 3.7793 (10) Å between the inversion-related benzene rings.

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2-(2,4-Dichloro­phen­yl)-2-oxoethyl 4-meth­oxy­benzoate

In the title compound, C(16)H(12)Cl(2)O(4), the dihedral angle between the benzene rings is 70.11 (6)°. In the crystal, mol-ecules are linked by C-H⋯O hydrogen bonds into a three-dimensional network. A C-H⋯π inter-action is also observed.

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2-(4-Fluoro­phen­yl)-2-oxoethyl 3-(trifluoro­meth­yl)benzoate

In the title compound, C(16)H(10)F(4)O(3), the fluoro-form group is disordered over two orientations with an occupancy ratio of 0.834 (4):0.166 (4). The dihedral angle between the two aromatic rings is 20.34 (9)°. In the crystal, C-H⋯O hydrogen bonds link the mol-ecules into layers lying parallel to the bc plane.

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عنوان ژورنال:

دوره 67  شماره 

صفحات  -

تاریخ انتشار 2011